2026-10-13T23:02:47Zhttps://www.radar-service.eu/oai/OAIHandler

10.22000/ab0bmuwhdgfs0tqq2026-10-09T11:51:09Zradar4chem

https://dx.doi.org/10.22000/ab0bmuwhdgfs0tqq Seitz, Tobias Karabulut, Aylin Hoffmann, Alexander Herres-Pawlis, Sonja Experimental Data to the publication "The Golden Goal of Entatic State Model Design: Lowering the Internal Reorganization Energy Leads to Exponential Increase in Electron Transfer Rate" RWTH Aachen University 2025 Chemistry dataset Dataset The measurements were performed with a METROHM AUTOLAB PGSTAT 101 potentiostat using a three-electrode arrangement with a Pt disc working electrode (1 mm diameter), a Pt wire as counter electrode and an Ag/AgCl (in saturated ethanolic LiCl) reference electrode. The measurements were performed in MeCN and 100 mmol/L NBu4PF6 with a sample concentration of 1 mmol/L at room temperature. Ferrocene was added as an internal standard after the measurements of the sample and all potentials are referenced relative to the Fc/Fc+ potential. Cyclic voltammograms were measured with 200 mV s –1, 100 mV s –1, 50 mV s –1 and 20 mV s –1. The stopped-flow measurements were performed with a HI-TECH Scientific SF-61SX2 device with a diode array detector. The optical light path for transmission of the quartz glass cuvette was 10 mm. The mixing time is given by HI-TECH to amount to 2 ms. UV/Vis spectra in a wavelength range of 300 nm to 800 nm were detected with temporal resolutions of 0.75 to 7.5 s. Instrument Instrument info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode Cyclic voltammetric data, UV/Vis spectroscopic data and DFT optimized structures of the complexes are deposited. electron transfer guanidine complexes electron self-exchange copper complexes eng 501100001659 application/x-tar