Experimental Data to the publication „Unraveling the Electron Transfer Mechanism in the Reduction of Bis(µ-oxido) Dicopper Complexes”

2026-06-22T01:46:36Zhttps://www.radar-service.eu/oai/OAIHandler

10.22000/drn56dwfku72hn162026-05-23T19:14:35Zradar4chem

10.22000/drn56dwfku72hn16 Schmidt, Regina Regina Schmidt 0000-0001-8049-4706 Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, 52074 Aachen, Germany Weinelt, Leander Leander Weinelt Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, 52074 Aachen, Germany Laurini, Larissa Larissa Laurini 0009-0000-6250-6451 Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, 52074 Aachen, Germany Becker, Nils Jannis Nils Jannis Becker Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, 52074 Aachen, Germany Hoffmann, Alexander Alexander Hoffmann 0000-0002-9647-8839 Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, 52074 Aachen, Germany Herres-Pawlis, Sonja Sonja Herres-Pawlis Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, 52074 Aachen, Germany Experimental Data to the publication „Unraveling the Electron Transfer Mechanism in the Reduction of Bis(µ-oxido) Dicopper Complexes” RWTH Aachen University 2020-2025 2026 Chemistry copper dioxygen Bis(µ-oxido) Dicopper Complexes ultraviolet-visible spectrophotometry kinetic spectroscopy electron transfer Rate Constant DFT calculation Data of UV/Vis spectroscopic titration measurements, of stopped-flow UV/Vis spectroscopic measurements and of CV measurements. Open Access Creative Commons Attribution Non Commercial Share Alike 4.0 International RWTH Aachen University https://ror.org/04xfq0f34 The dataset contains measurement and evaluation data from UV/Vis spectroscopic titration measurements, stopped-flow UV/Vis spectroscopic measurements and CV measurements. Agilent Technologies Cary 60 spectrophotometer connected via a Cary 50 fiber optic coupler and combined with a fiber-optic quartz glass immersion probe (Hellma, 1 mm) HI-TECH Scientific SF-61SX2 device from TgK Scientific with a charge-coupled device (CCD) photodiode array detector and a xenon arc lamp as light source. The optical path length of the quartz glass cuvette was 10 mm and the mixing time amounts to 2 ms. a Metrohm Autolab PGSTAT 101 potentiostat with a three-electrode arrangement with a Pt disc working electrode (1 mm diameter), an Ag wire pseudo reference electrode and a glassy-carbon counter electrode en 1,1 GB application/x-tar