2026-10-11T20:08:04Zhttps://www.radar-service.eu/oai/OAIHandler

10.22000/snmphx276tt041sa2026-10-09T11:51:00Zradar4chem

https://dx.doi.org/10.22000/snmphx276tt041sa Seitz, Tobias Walbeck, Marcel Hoffmann, Alexander Herres-Pawlis, Sonja Experimental Data to the publication ""Electron transfer kinetics of a series of copper complexes with tripodal tetradentate guanidine quinolinyl ligands" RWTH Aachen University 2024 Chemistry dataset Optimized coordinates otained from DFT calculations, Cyclic Voltammetry measurements and stopped-flow UV/Vis spectroscic data Dataset The stopped-flow measurements were performed with a HI-TECH Scientific SF-61SX2 device with a diode array detector. The optical light path for transmission of the quartz glass cuvette was 10 mm. The measurements were performed with a METROHM AUTOLAB PGSTAT 101 potentiostat using a three-electrode arrangement with a Pt disc working electrode (1 mm diameter), a Pt wire as counter electrode and an Ag/AgCl (in saturated ethanolic LiCl) reference electrode. The measurements were performed in MeCN and 100 mmol/L NBu4PF6 with a sample concentration of 1 mmol/L at room temperature. Ferrocene was added as an internal standard after the measurements of the sample and all potentials are referenced relative to the Fc/Fc+ potential. Cyclic voltammograms were measured with 200 mV·s–1, 100 mV·s–1, 50 mV·s–1 and 20 mV·s–1. Instrument Instrument info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-sa/4.0/legalcode Optimized coordinates otained from DFT calculations, Cyclic Voltammetry measurements and results of stopped-flow UV/Vis spectroscic measurements were deposited. DFT optimized coordinates Stopped-flow UV/Vis spectroscopic measurements cyclic voltammetry eng 501100001659 application/x-tar