2026-10-07T18:16:28Zhttps://www.radar-service.eu/oai/OAIHandler

10.35097/9372023-11-15T14:44:10Zradar4kit

https://dx.doi.org/10.35097/937 Welle, Alexander Gold nanoclusters inside the metal-organic framework HKUST-1 Karlsruhe Institute of Technology 2023 Materials Science dataset Dataset info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/4.0/legalcode Hassan, Zeinab Mohamed Guo, Wei Oestreich, Robert Janiak, Christoph Redel, Engelbert Gas phase infiltration of the carbonylchloridogold(I), Au(CO)Cl precursor into the pores of HKUST-1 ([Cu3(BTC)2(H2O)2], Cu-BTC) SURMOFs (surface-mounted metal-organic frameworks; BTC = benzene-1,3,5-tricarboxylate) leads to Au(CO)Cl decomposition within the MOF through hydrolysis with the aqua ligands on Cu. Small Aux clusters with an average atom number of x ≈ 5 are formed in the medium-sized pores of the HKUST-1 matrix. These gold nanoclusters are homogeneously distributed and crystallographically ordered, which was supported by simulations of the powder X-ray diffractometric characterization. Aux@HKUST-1 was further characterized by time-of-flight secondary ion mass spectrometry (ToF-SIMS). Goldcarbonyl chloride Gold nanoclusters Metal-organic frameworks Hassan, Zeinab Mohamed Guo, Wei Oestreich, Robert Janiak, Christoph Redel, Engelbert 10.3390/molecules28062716 application/x-tar