2026-10-13T16:57:12Zhttps://www.radar-service.eu/oai/OAIHandler

10.35097/xayn6n5pmcvdk7762026-10-09T11:00:16Zradar4kit

https://dx.doi.org/10.35097/xayn6n5pmcvdk776 Weber, Frank Heid, Rolf Merz, Michael Eich, Andreas Tymoshenko, Yuliia Merritt, Adrian M. Phonons reflect dynamic spin-state order in LaCoO$_3$ Karlsruhe Institute of Technology 2026 Physics dataset Dataset info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-sa/4.0/legalcode We investigate lattice dynamics in LaCoO₃ using inelastic neutron and x-ray scattering over T = 2–650 K, spanning the spin-state crossover at T₁ ≈ 100 K and the insulator–metal transition at T₂ ≈ 550 K. Comparison with quasi-harmonic ab-initio lattice-dynamical calculations helps reveal anomalous softening of a ≈10-meV oxygen phonon, confined to the temperature interval T₁ ≤ T ≤ T₂ and localized in momentum space at qSSO = (½,½,½)c. This wave vector corresponds to the spin-state ordering originally proposed by Goodenough [J. Phys. Chem. Solids 6, 287-297 (1958)]. Our results therefore provide momentum-resolved evidence for dynamic correlations of high-spin and low-spin Co³⁺ states in LaCoO₃, linking spin-state fluctuations to anomalous phonon renormalization. Data as published in Figures 1-5 of the corresponding manuscript. https://publikationen.bibliothek.kit.edu/1000189793 application/x-tar