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    Dataset: Experimental Data to the publication ""Electron transfer kinetics of a series of copper complexes with tripodal tetradentate guanidine quinolinyl ligands"

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    Creator/Author:
    Seitz, Tobias https://orcid.org/0009-0003-4039-3953 [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]

    Walbeck, Marcel [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]

    Hoffmann, Alexander https://orcid.org/0000-0002-9647-8839 [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]

    Herres-Pawlis, Sonja https://orcid.org/0000-0002-4354-4353 [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]
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    Title:
    Experimental Data to the publication ""Electron transfer kinetics of a series of copper complexes with tripodal tetradentate guanidine quinolinyl ligands"
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    Description:
    (Abstract) Optimized coordinates otained from DFT calculations, Cyclic Voltammetry measurements and results of stopped-flow UV/Vis spectroscic measurements were deposited.
    Keywords:
    DFT optimized coordinates
    Stopped-flow UV/Vis spectroscopic measurements
    cyclic voltammetry
    Related information:
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    Language:
    English
    Publishers:
    RWTH Aachen University
    Production year:
    Subject areas:
    Chemistry
    Resource type:
    (Dataset) Optimized coordinates otained from DFT calculations, Cyclic Voltammetry measurements and stopped-flow UV/Vis spectroscic data
    Data source:
    (Instrument) The stopped-flow measurements were performed with a HI-TECH Scientific SF-61SX2 device with a diode array detector. The optical light path for transmission of the quartz glass cuvette was 10 mm.
    (Instrument) The measurements were performed with a METROHM AUTOLAB PGSTAT 101 potentiostat using a three-electrode arrangement with a Pt disc working electrode (1 mm diameter), a Pt wire as counter electrode and an Ag/AgCl (in saturated ethanolic LiCl) reference electrode. The measurements were performed in MeCN and 100 mmol/L NBu4PF6 with a sample concentration of 1 mmol/L at room temperature. Ferrocene was added as an internal standard after the measurements of the sample and all potentials are referenced relative to the Fc/Fc+ potential. Cyclic voltammograms were measured with 200 mV·s–1, 100 mV·s–1, 50 mV·s–1 and 20 mV·s–1.
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    Gaussian 16 - Revision B01
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    Chemcraft - 1.8
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    Resource viewing
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    notepad - 7.8.1
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    Kinetic Studio - 4.0.8.18533
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    Resource viewing
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    OriginPro 2021b - 9.8.5.212
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    Resource production
    Software:
    NOVA from Metrohm Autolab - 2.1.5 (Build 7691)
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    Publication year:
    Rights holders:
    RWTH Aachen University
    Funding:
    Deutsche Forschungsgemeinschaft - (Kontrolle des entatischen Zustands durch die gezielte optische Anregung der Ligandensphäre) 413524714
    Name Storage Metadata Upload Action
    Status:
    Published
    Uploaded by:
    iac_Radar_Produktion
    Created on:
    Archiving date:
    2024-11-16
    Archive size:
    548.5 MB
    Archive creator:
    iac_Radar_Produktion
    Archive checksum:
    e6eae8992431c213d5edc0df1d2eb740 (MD5)
    Embargo period:
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